龚军芳，博士、教授、博士生导师，河南省教育厅学术技术带头人(2004)，河南省高等学校精品资源共享课《有机化学》课程负责人(2014)。
邮箱：gongjf@zzu.edu.cn
研究方向：金属有机化学。近年来主要对三齿配位钳形金属化合物的设计、合成、光致发光和催化性能及其相关应用进行了研究，同时也开展了一些导向基包括手性导向基辅助的、过渡金属催化C-H键官能团化反应研究。
教育与工作简历：
2010.04-至今 郑州大学化学学院(原化学系)教授
2003.03-2010.03 郑州大学化学系副教授
2001.10-2003.02 法国巴黎国家高等化学学校 (ENSCP, 现ParisTech)博士后
1999.10-2001.09 郑州大学化学系博士后
1995.09-1998.09 中国科学院化学研究所博士
1992.09-1995.06 南开大学化学系硕士
1988.09-1992.06 南开大学化学系学士
代表性教学成果与荣誉：
2008年宝钢优秀教师奖
2010年河南省教育系统教学技能竞赛(高校化学)一等奖并获“河南省教学标兵”称号
2015年郑州大学“三育人”先进个人(2014~2015学年)
2015年郑州大学第八届教学名师奖
主持科研项目：
1. 2015.01-2018.12国家自然科学基金面上项目 “手性钳形铱化合物的合成、负载化及其催化不对称卡宾插入反应” (21472176)
2. 2010.01-2012.12国家自然科学基金面上项目“混合给体钳形镍化合物的合成、结构及其在催化反应中的应用” (20972141)
3. 2012.01-2014.12河南省高校科技创新人才支持计划资助项目 “手性钳形钯化合物催化剂的合成与应用研究” (2012HASTIT003)
4. 2010.01-2012.12河南省科技攻关重大项目 “非对称三齿配位钯化合物的催化性能研究” (102101210200)
5. 2010.01-2012.12河南省高等学校青年骨干教师资助计划 “含氮杂环卡宾的钯和镍化合物的合成与催化性能研究” (2010GGJS-015)
代表性论文：
1. Nan Li, Xiaoyan Yang, Yanyan Zhu, Fang Wang,Junfang Gong*, Maoping Song*. “Pincer iridium(III)-catalyzed enantioselective C(sp3)-H functionalization via carbenoid C-H insertion of 3-diazooxindoles with 1,4-cyclohexadiene.” Chin. Chem. Lett. 2022,33, 2437-2441.
2. Xue-Hong Li,Jun-Fang Gong*, Mao-Ping Song*. “Microwave-Assisted Ruthenium- and Rhodium-Catalyzed Couplings ofα-Amino Acid Ester-Derived Phosphinamides with Alkynes.” Chem.Asian J. 2022,17, e202101158.
3. Jun-Jian Huang, Xiao-Qi Zhang, Jing-Jing Yang, Jun-Fang Gong*, Mao-Ping Song*. “Chiral (phosphine)-(imidazoline) PCN pincer palladium(II) complexes: synthesis and application in asymmetric hydrophosphination of 2-alkenoylpyridines with diphenylphosphine.” Dalton Trans. 2022,51, 8350-8367.
4. Xue-Hong Li, Guang-Chao Yang,Jun-Fang Gong*, Mao-Ping Song*. “Copper-catalyzed regioselective C2-H chlorination of indoles with para-toluenesulfonyl chloride.” Org. Biomol. Chem. 2022,20, 4815-4825.
5. Yi-Dong Wang, Jin-Kui Liu, Xue-Jie Yang,Jun-Fang Gong*, Mao-Ping Song*. “Chiral (Pyridine)-(Imidazoline) NCN′ Pincer Palladium(II) Complexes:Convenient Synthesis via C−H Activation and Characterization.” Organometallics 2022,41, 984-996.
6. Xue-Hong Li,Jun-Fang Gong*, Mao-Ping Song*. “Diastereoselective synthesis of chiral 3-substituted isoindolinones via rhodium(III)-catalyzed oxidative C–H olefination/annulation.” Org. Biomol. Chem. 2021,19, 5876-5887.
7. Ya-Ping Pan, Nan Li, Jing-Jing Yang, Zhi-Wu Zhu,Jun-Fang Gong*, Mao-Ping Song. “Facile synthesis of NC(sp3)O pincer palladium complexes and their use as efficient catalysts for Suzuki-Miyaura reaction of aryl bromides in aqueous medium.”J. Organomet. Chem. 2021,932, 121645.
8. Yang Li,Jun-Fang Gong*, Mao-Ping Song*. “Palladium-catalyzed δ-selective reductive Heck reaction of alkenyl carbonyl compounds with aryl iodides and bromides.” Org. Chem. Front. 2020,7(16), 2216-2223.
9. Wen-Jing Zhu,Jun-Fang Gong*, Mao-Ping Song*. “Synthesis of Chiral Bis(3-indolyl)methanes Bearing a Trifluoromethylated All-Carbon Quaternary Stereocenter via Nickel-Catalyzed Asymmetric Friedel−Crafts Alkylation Reaction.”J. Org. Chem. 2020,85(15), 9525-9537.
10. Nan Li, Wen-Jing Zhu, Juan-Juan Huang, Xin-Qi Hao,Jun-Fang Gong*, Mao-Ping Song*. “Chiral NCN Pincer Iridium(III) Complexes with Bis(imidazolinyl)phenyl Ligands: Synthesis and Application in Enantioselective C-H Functionalization of Indoles with α-Aryl-α-diazoacetates.” Organometallics2020,39(12), 2222-2234.
11. Cong Wang, Nan Li, Wen-Jing Zhu,Jun-Fang Gong*, Mao-Ping Song*. “Asymmetric Michael Addition of 2-Acetyl Azaarenes to β-CF3-β-(3-indolyl)nitroalkenes Catalyzed by a Cobalt(II)/(imidazoline-oxazoline) Complex.”J. Org. Chem. 2019,84(1), 191-203.
12. Invited review: Jin-Kui Liu,Jun-Fang Gong*, Mao-Ping Song*. “Chiral palladium pincer complexes for asymmetric catalytic reactions.”Org. Biomol. Chem. 2019,17(25), 6069-6098. (封面文章)
13. Jun-Ru Guo,Jun-Fang Gong*, Mao-Ping Song*. “Nickel(II)-catalyzed C(sp2)–H sulfuration/annulation with elemental sulfur: selective access to benzoisothiazolones.”Org. Biomol. Chem. 2019,17(20), 5029-5037.
14. Cong Wang, Yang Li, Beibei Lu, Xin-Qi Hao,Jun-Fang Gong*, Mao-Ping Song*. “(Phosphinito)aryl benzimidazole PCN pincer palladium(II) complexes: Synthesis, characterization and catalytic activity in C-H arylation of azoles with aryl iodides.”Polyhedron 2018,143, 184-192.
15. Shuang-Liang Liu, Yang Li, Jun-Ru Guo, Guang-Chao Yang, Xue-Hong Li,Jun-Fang Gong*, Mao-Ping Song*. “An Approach to 3-(Indol-2-yl)succinimide Derivatives by Manganese-Catalyzed C-H Activation.”Org. Lett.2017,19(15),4042-4045.
16. Shuang-Liang Liu, Xue-Hong Li, Shu-Sheng Zhang, Sheng-Kai Hou, Guang-Chao Yang,Jun-Fang Gong*, Mao-Ping Song*. “Nickel-Catalyzed Sulfonylation of C(sp2)-H Bonds with Sodium Sulfinates.”Adv. Synth. Catal. 2017,359(13), 2241-2246.
17. Xin-Qi Hao, Cong Wang, Shuang-Liang Liu, Xiao Wang, Li Wang,Jun-Fang Gong*, Mao-Ping Song*. “Cobalt(II)/(imidazoline-oxazoline)-catalyzed enantioselective Michael addition of 2-acetyl azaarenes to β-CF3-β-disubstituted nitroalkenes.”Org. Chem. Front. 2017,4(2), 308-312.
18. Shuang-Liang Liu, Xue-Hong Li, Tan-Hao Shi, Guang-Chao Yang, Hai-Li Wang,Jun-Fang Gong*, Mao-Ping Song*. “Copper-Promoted Thiolation of C(sp2)–H Bonds Using a 2-Amino Alkylbenzimidazole Directing Group.”Eur. J. Org. Chem.2017,2017(16), 2280-2289.
19. Xin-Qi Hao, Juan-Juan Huang, Tao Wang, Jing Lv, Jun-Fang Gong*, Mao-Ping Song*. “PCN Pincer Palladium(II) Complex Catalyzed Enantioselective Hydrophosphination of Enones: Synthesis of Pyridine-Functionalized Chiral Phosphine Oxides as NCsp3O Pincer Preligands.” J. Org. Chem. 2014, 79(20), 9512-9530.
20. Xin-Qi Hao, Yong-Wei Zhao, Jing-Jing Yang, Jun-Long Niu,Jun-Fang Gong*, Mao-Ping Song*. “Enantioselective Hydrophosphination of Enones with Diphenylphosphine Catalyzed by Bis(imidazoline) NCN Pincer Palladium(II) Complexes.”Organometallics2014,33(7), 1801-1811.
21. Zhao Wang, Zheming Sun, Xin-Qi Hao, Jun-Long Niu, Donghui Wei, Tao Tu,Jun-Fang Gong*, Mao-Ping Song*. “Neutral and Cationic NCN Pincer Platinum(II) Complexes with 1,3-Bis(benzimidazol-2'-yl)benzene Ligands: Synthesis, Structures, and Their Photophysical Properties.”Organometallics2014,33(7), 1563-1573.
22. Tao Wang, Xin-Qi Hao, Juan-Juan Huang, Kai Wang,Jun-Fang Gong*, Mao-Ping Song*. “Chiral CNN Pincer Palladium(II) Complexes with 2-Aryl-6-(Oxazolinyl)pyridine Ligands: Synthesis, Characterization, and Application to Enantioselective Allylation of Isatins and Suzuki-Miyaura Coupling Reaction.”Organometallics2014,33(1), 194-205.
23. Tao Wang, Xin-Qi Hao, Juan-Juan Huang, Jun-Long Niu,Jun-Fang Gong*, Mao-Ping Song*. “Chiral Bis(imidazolinyl)phenyl NCN Pincer Rhodium(III) Catalysts for Enantioselective Allylation of Aldehydes and Carbonyl-Ene Reaction of Trifluoropyruvates.”J. Org. Chem.2013,78(17), 8712-8721.
24. Tao Wang, Jun-Long Niu, Shuang-Liang Liu, Juan-Juan Huang,Jun-Fang Gong*, Mao-Ping Song*. “Chiral NCN Pincer Rhodium(III) Complexes with Bis(imidazolinyl)phenyl Ligands: Synthesis and Enantioselective Catalytic Alkynylation of Trifluoropyruvates with Terminal Alkynes.”Adv. Synth. Catal. 2013,355(5), 927-937. (Highlighted bySynfacts 2013, 9(6), 0636)
25. 研究专题：郝新奇, 牛俊龙, 赵雪梅,龚军芳*, 宋毛平*. “第VIII族钳形金属催化剂的研究进展.” 有机化学 2013,33(4), 663-674.
26. Xin-Qi Hao, Yan-Xiao Xu, Ming-Jun Yang, Li Wang, Jun-Long Niu,Jun-Fang Gong*, Mao-Ping Song*. “A Cationic NCN Pincer Platinum(II) Aquo Complex with a Bis(imidazolinyl) phenyl Ligand: Studies toward its Synthesis and Asymmetric Friedel−Crafts Alkylation of Indoles with Nitroalkenes.”Organometallics 2012,31(3), 835-846.
27. Ming-Jun Yang, Yan-Jing Liu,Jun-Fang Gong*, Mao-Ping Song*. “Unsymmetrical Chiral PCN Pincer Palladium(II) and Nickel(II) Complexes with Aryl-Based Aminophosphine-Imidazoline Ligands: Synthesis via Aryl C-H Activation, and Asymmetric Addition of Diarylphosphines to Enones.”Organometallics 2011,30(14), 3793-3803.
28. Invited Perspective: Jun-Long Niu, Xin-Qi Hao,Jun-Fang Gong*, Mao-Ping Song*. “Symmetrical and unsymmetrical pincer complexes with group 10 metals: Synthesis via aryl C–H activation and some catalytic applications.”Dalton Trans. 2011,40(19), 5135-5150.
29. Tao Wang, Xin-Qi Hao, Xiao-Xue Zhang,Jun-Fang Gong*, Mao-Ping Song*. “Synthesis, structure and catalytic properties of CNN pincer palladium(II) and ruthenium(II) complexes with N-substituted-2-aminomethyl-6-phenyl pyridines.”Dalton Trans.2011,40(35), 8964-8976. (封面文章)
30. Dan-Dan Shao, Jun-Long Niu, Xin-Qi Hao,Jun-Fang Gong*, Mao-Ping Song*. “Neutral and cationic chiral NCN pincer nickel(II) complexes with 1,3-bis(2'-imidazolinyl) benzenes: synthesis and characterization.”Dalton Trans.2011,40(35), 9012-9019.
31. Ben-Shang Zhang, Wei Wang, Dan-Dan Shao, Xin-Qi Hao,Jun-Fang Gong*, Mao-Ping Song*. “Unsymmetrical Chiral PCN Pincer Palladium(II) and Nickel(II) Complexes of (Imidazolinyl)aryl Phosphinite Ligands: Synthesis via Ligand C-H Activation, Crystal Structures and Catalytic Studies.”Organometallics 2010,29(11), 2579-2587.
32. Jun-Long Niu, Qing-Tao Chen, Xin-Qi Hao, Qing-Xiang Zhao,Jun-Fang Gong*, Mao-Ping Song*. “Diphenylprolinol-derived Symmetrical and Unsymmetrical Chiral Pincer Palladium(II) and Nickel(II) Complexes: Synthesis via One-Pot Phosphorylation/metalation Reaction and C-H Activation.”Organometallics 2010,29(9), 2148-2156.
33. Li-Yuan Wu, Xin-Qi Hao, Yan-Xiao Xu, Min-Qiang Jia, Ya-Nan Wang,Jun-Fang Gong*, Mao-Ping Song*. “Chiral NCN Pincer Pt(II) and Pd(II) Complexes with 1,3-Bis(2'-imidazolinyl)benzene: Synthesis via Direct Metalation, Characterization, and Catalytic Activity in the Friedel-Crafts Alkylation Reaction.”Organometallics 2009,28(12), 3369-3380.
34. Jun-Fang Gong, Yan-Hui Zhang, Mao-Ping Song*, Chen Xu. “New PCN and PCP Pincer Palladium(II) Complexes: Convenient Synthesis via Facile One-pot Phosphorylation/Palladation Reaction and Structural Characterization.”Organometallics 2007,26(25), 6487-6492.
35. An-Ting Hou, Yan-Jing Liu, Xin-Qi Hao,Jun-Fang Gong*, Mao-Ping Song*. “Synthesis and Characterization of new (pyrazolyl)aryl phosphinite PCN pincer palladium(II) complexes.”J. Organomet. Chem.2011,696(15-16), 2857-2862.
36. Xin-Qi Hao, Ya-Nan Wang, Jun-Rui Liu, Kun-Lun Wang,Jun-Fang Gong*, Mao-Ping Song*. “Unsymmetrical, oxazolinyl-containing achiral and chiral NCN pincer ligand precursors and their complexes with palladium(II).”J. Organomet. Chem. 2010,695(1), 82-89.
37. Ben-Shang Zhang, Chao Wang,Jun-Fang Gong*, Mao-Ping Song*. “Facile synthesis of achiral and chiral PCN pincer palladium(II) complexes and their application in the Suzuki and copper-free Sonogashira cross-coupling reactions.”J. Organomet. Chem. 2009,694(16), 2555-2561.
38. Xin-Qi Hao,Jun-Fang Gong*, Chen-Xia Du, Li-Yuan Wu, Yang-Jie Wu, Mao-Ping Song*. “Synthesis, characterization and photoluminescent properties of platinum complexes with novel bis(imidazoline) pincer ligands.”Tetrahedron Lett. 2006,47(29), 5033-5036.
参与翻译、编写的著作：
1. 宋毛平，毛璞，廖新成，张雁冰，龚军芳. 有机立体化学导论(译著, 国外名校名著系列), 化学工业出版社, 2007.1
2.龚军芳. 傅瑞德尔-克拉夫兹反应 P43-96 (现代有机反应第5卷 金属催化反应 胡跃飞 林国强主编)，化学工业出版社，2008.12
3.龚军芳, 宋毛平. 玉尾-熊田-弗莱明立体选择性羟基化反应 P277-340 (现代有机反应第8卷 碳-杂原子键参与的反应II 胡跃飞 林国强主编)，化学工业出版社，2013.1
4.Jun-Fang Gong, Xinju Zhu and Mao-Ping Song. “Chapter 9 Transition Metal Pincer Complexes With Chiral Imidazoline Donor(s): Synthesis and Asymmetric Catalysis.” InPincer Compounds: Chemistry and Applications. Ed. by David Morales-Morales, Elsevier, Amsterdam, P191-218, ISBN: 978-0-12-812931-9, 2018.5.
科技奖励：
教育部高等学校科学研究优秀成果奖二等奖，金属有机化合物在催化偶联与制备发光材料中的应用，2014年1月，第5完成人(共9人)
