郑州大学, 化学学院, 副教授,郑州大学化学国家级实验教学示范中心主任,河南省化学会理事。2008年、2014年在清华大学化学系先后获得理学学士学位和理学博士学位,师从童爱军教授;2012年、2017年两次作为访问学者在香港科技大学进行访问学习,师从唐本忠院士。主要研究方向为发光币金属团簇的开发和新型AIE体系的构建,先后以通讯作者或第一作者身份发表相关 SCI 论文50 余篇,包括J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、Natl. Sci. Rev.、CCS Chem.、Chem.Sci.、Adv. Sci.等优秀学术期刊,主持国家自然科学基金河南联合基金、国家自然科学基金青年基金、河南省自然科学基金优秀青年基金、河南省科技创新人才等科研项目。
联系方式:
likai@zzu.edu.cn
学习经历:
2004.8-2008.7,清华大学化学系学习,获得理学学士学位。
2009.8-2014.7,清华大学化学系学习,获得理学博士学位。
导师:童爱军教授
2012.7-2012.9,香港科技大学,交换生。
导师:唐本忠院士
2017.3-2017.9,香港科技大学,访问学者。
工作经历:
2008.8-2009.7,青海大学应用化学系支教(团中央扶贫接力计划-清华大学第十届研究生支教团项目)
2014-今,郑州大学化学学院工作
研究方向:
聚集诱导发光,发光币金属簇
主持项目:
1. 国家自然科学基金河南联合基金——基于聚集诱导发光(AIE)分子的新型有机光响应荧光材料。
2. 国家自然科学基金青年基金——基于螺内酰肼水杨醛希夫碱金属配合物的新型光响应体系。
3. 2022年度河南省高校科技创新人才——具有聚集诱导发光(AIE)性能的币金属团簇材料的理性构筑与性能研究。
4. 河南省自然科学基金优秀青年基金——具有聚集诱导发光(AIE)性能的刺激响应型货币金属团簇。
5. 2022河南省高等教育教学改革研究与实践项目重点项目——以“聚集诱导发光(AIE)”理论为载体开展课程思政建设的研究与实践。
代表论文:
1. Peng, Q. C.; Luo, X. M.; Qin, Y. J.; Wang, T.; Bai, B.; Wei, X. L.;Li, K.*; Zang, S.*, Influence of Wallach’s Rule on Chiral AIE Systems and Its Application in Cryptographic Information Storage.CCS Chem. 2022, https://doi.org/10.31635/ccschem.022.202201998
2. Su, H. F.*; Peng, Q. C.; Liu, Y. U.; Xie, T.; Liu, P. P.;Cai, Y. C.; Wen, W.; Yu, Y. H.;Li, K.*; Zang, S. Q.*, A Near-infrared AIE probe and its Applications for Specific In Vitro and In Vivo Two-Photon Imaging of Lipid Droplets, Biomaterials,2022,288, 121691.
3. Liu, Y.; Zhang, X.;Li, K.*; Peng, Q.; Qin, Y.; Hou, H.*; Zang, S.*; Tang, B. Z.*, Restriction of Intramolecular Vibration in Aggregation-Induced Emission Luminogens: Applications in Multifunctional Luminescent Metal-Organic Frameworks.Angew. Chem. Int. Ed. 2021, 60, 22417-22423.
4. Jin,Y.; Peng, Q.; Li, S.; Su, H. F.; Luo, P.; Yang, M.; Zhang, X.;Li, K.*; Zang, S.*; Tang, B. Z.*; Mak, T. C. W., Aggregation-induced barrier to oxygen (AIBO) - A new AIE mechanism for metal cluster with phosphorescence.Natl. Sci. Rev.,2022, DOI: 10.1093/nsr/nwab216
5. Kong, Y.; Yan, Z.; Li, S.; Su, H.;Li, K.*; Zheng Y.; Zang, S.*, Photo-responsive propeller-like chiral AIE Cu(I) clusters.Angew. Chem. Int. Ed. 2020,53, 5336-5340.
6. Xing, C.; Liu, J.; Chen, F.; Li, Y.*; Lv, C.; Peng, Q.; Hou, H.*;Li, K.*, Diphenyl-1-pyrenylphosphine: Photo-triggered AIE/ACQ transition with remarkable optical signal change.Chem. Commun.2020,56, 4220-4223.
7. Peng,Q.; Yang, L.; Li, Y.; Zhang, Y.; Li, T.; Qin, Y.; Song, Y.; Hou, H.*; Li, K.*, Aggregation/viscosity-induced emission and third-order nonlinear optical signal inversion in a TICT system.J. Phys. Chem. C 2020,124, 22684-22691.
8. Zhang, M.;Li, K.*; Zang, S.*, Progress in atomically precise coinage metal clusters with AIE and CPL. Adv. Opt. Mater. 2020,8, 1902152.
9. Xing, C.; Liu, J.; Yang, L.; Shao, Z.; Xu, W.; Zhao, Y.;Li, K.*; Song, Y.; Hou, H.*, Third-order nonlinear optical adjusting behavior in azobenzene metal complexes. Sci. China Mater. 2020,64, 408-419.
10. Liu, Y.; Peng, Q.; Li, Y.; Hou, H.*;Li, K.*, A simple strategy for constructing acylhydrazone photochromic system with visible color/emission change and its application in photo-patterning. Chin. Chem. Lett. 2020, 31, 3271-3275.
11. Wu, X.; Wei, Z.; Yan, B.; Huang, R.; Liu, Y.;Li, K.*; Zang, S.*; Mak, T. C. W., Mesoporous crystalline silver chalcogenolate cluster assembled-material with tailored photo-luminescence properties.CCS Chem.2019,1, 553-560.
12. Sun, K.; Chen, X.*; Zhang, Y.;Li, K.*; Huang, X.; Peng, Y.; Qu, L.; Yu, B.*, Metal-free sulfonyl radical-initiated cascade cyclization to access sulfonated indolo[1,2-a]quinolines. Chem. Commun. 2019,55, 12615-12618.
13. Wei, Z.; Wu, X.; Luo, P.; Wang, J.;Li, K.*; Zang, S.*, Matrix coordination induced emission in a three-dimensional silver cluster-assembled material.Chem. Eur. J.2019,25, 2750-2756.
14. Wu, X. H.; Luo, P.; Wei, Z.; Liu, Y. Y.; Huang, R. W.; Dong, X. Y.;Li, K.*; Zang, S. Q.*; Tang, B. Z.*, Guest-triggered aggregation-induced emission in silver chalcogenolate cluster metal-organic frameworks.Adv. Sci. 2019,6, 1801304.
15. Xu, K.; Li, Y.*; Su, H.; Wang, B.; Sun, K.; Liu, Y.; Peng, Q.; Hou, H.*;Li, K.*, Photo-induced free radical production in a tetraphenylethylene ligand-based metal-organic framework.Chem. Commun. 2018,54, 12942-12945.
16. Li, K.*; Feng, Q.; Niu, G.; Zhang, W.; Li, Y.; Kang, M.; Xu, K.; He, J.; Hou, H.*; Tang, B. Z.*, Benzothiazole-basedAIEgen with tunable excited-state intramolecular proton transfer and restricted intramolecular rotation processes for highly sensitive physiological pH sensing.ACS Sens. 2018,3, 920-928.
17. Sun, K.; Chen, X. L.*; Li, S. J.; Wei, D. H.; Liu, X. C.; Zhang, Y. L.; Liu, Y.; Fan, L. L.; Qu, L. B.; Yu, B.*;Li, K.*; Sun, Y., Q.*; Zhao, Y. F., Copper-catalyzed radical cascade cyclization to access 3-sulfonated indenones with the AIE Phenomenon.J. Org. Chem. 2018,83,14419-14430.
18. Li, K.*; Liu, Y.; Li, Y.; Feng, Q.; Hou, H.*; Tang, B. Z.*, 2, 5-bis(4-alkoxycarbonylphenyl)-1,4-diaryl-1,4-dihydropyrrolo[3,2-b]pyrrole (AAPP) AIEgens: tunable RIR and TICT characteristics and their multifunctional applications. Chem. Sci. 2017, 8, 7258-7267.
19. Wang, J.; Li, Y.;Li, K.*; Meng, X.; Hou, H.*, Highly selective turn-on fluorescent chemodosimeter for Al(III) detection via Al(III)‐promoted hydrolysis of carbon‐nitrogen double bond in 8-hydroxyquinoline aldehyde Schiff base.Chem. Eur. J.2017, 23, 5081-5089.
20. Li, Y.;Li, K.*; Wang, L.; He, Y.; He, J.; Hou, H.*; Tang, B. Z.*, Fluoran salicylaldehyde hydrazone Zn(II) complexes: reversible photochromic systems both in solution and in a solid matrix.J. Mater. Chem. C 2017,5(30), 7553-7560.
21. Wang, L.; Li, Y.; You, X.; Xu, K.; Feng, Q.; Wang, J.; Liu, Y.;Li, K.*; Hou, H.*, An erasable photo-patterning material based on a specially designed 4-(1, 2, 2-triphenylvinyl) aniline salicylaldehyde hydrazone aggregation-induced emission (AIE) molecule. J. Mater. Chem. C 2017, 5 (1), 65-72.
22. Feng, Q.; Li, Y.; Wang, L.; Li, C.; Wang, J.; Liu, Y.;Li, K.*; Hou, H.*, Multiple-color aggregation-induced emission (AIE) molecules as chemodosimeters for pH sensing.Chem. Commun. 2016, 52 (15), 3123-3126.
23. Feng, Q.; Li, Y.; Shi, G.; Wang, L.; Zhang, W.;Li, K.*; Hou, H.*; Song, Y.*, A photo-controllable third-order nonlinear optical (NLO) switch based on a rhodamine B salicylaldehyde hydrazone metal complex.J. Mater. Chem. C 2016, 4 (36), 8552-8558.
24. Li, K.; Xiang, Y.; Wang, X.; Li, J.; Hu, R.; Tong, A.*; Tang, B. Z.*, Reversible photochromic system based on rhodamine B salicylaldehyde hydrazone metal complex.J. Am. Chem. Soc.2014, 136 (4), 1643-1649.
25. Li, K.; Xiang, Y.; Tong, A.*; Tang, B. Z.*, Readily accessible Rhodamine B-based photoresponsive material.Sci. China Chem.2014, 57 (2), 248-251.