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石林林

石林林,直聘副教授,硕士生导师

联系方式:linlinshi@zzu.edu.cn

学习和工作经历:

2014--2019北京大学(直博),博士(导师:杨震,龚建贤教授)

2019-至今 郑州大学化学学院,直聘副教授

研究方向:

超分子自组装,超分子催化,有机合成

所获荣誉:

北京大学三好学生;北京大学优秀学生干部;

北京大学五四奖学金;药明康德学术二等奖学金;

北京大学-普林斯顿双边论坛-优秀奖学金

主持项目:

中国博士后面上基金

国家自然科学基金青年基金

郑州大学拔尖启动基金

代表性论文:

(1)Yuanyuan Chang,Linlin Shi, Jun Huang, Lili Shi, Zichun Zhang, Hong-Dong Hao, Jianxian Gong and Zhen Yang. Stereoselective Total Synthesis of (±)-5-epi-Cyanthiwigin I via an Intramolecular Pauson−Khand Reaction as the Key Step.Org. Lett.2018, 20, 2876-2879.

(2)Linlin Shi, Yingdong He, Yuanyuan Chang, Nan Zheng, Zhen Yang, and Jianxian Gong. Stereoselective Pd-Catalyzed Decarboxylative Allylation: Assembly of Highly Functionalized Allylic Amines Bearing a Quaternary Center.Org. Lett. 2019, 21, 3077-3080.

(3)Linlin Shi, Yingdong He, Jianxian Gong and Zhen Yang. Pd-Catalyzed Decarboxylative Allylation for Stereoselective Syntheses of Allylic Alcohols bearing a Quaternary Carbon Center.AsianJ. Org. Chem.2019, 8, 823-827.

(4)Linlin Shi, Yingdong He, Jianxian Gong and Zhen Yang. Concise gram-scale synthesis of Euphorikanin A skeleton through a domino ring-closing metathesis strategy.Chem. Commun.2020, 56, 531-534.

(5)Linlin Shi, Yingdong He, Jianxian Gong and Zhen Yang. Palladium-Catalyzed Domino Decarboxylation/Carbonylation/ Cyclization Process for the Synthesis of Highly Substituted δ-Lactones and lactams.Organometallics.2020. doi.org/10.1021/acs.organomet.0c00646.

(6)Changlei Zhi, Qiuling Wang, Shuang Liu, Yuting Xue,Linlin Shi,*Xinju Zhu, Xin-Qi Hao, and Mao-Ping Song.* Cu-Catalyzed Direct C7-Sulfonylation of Indolines with Arylsulfonyl Chlorides.J. Org. Chem.2020, 85, 1022-1032.

(7)Zilin Liu, Xiaojie Zhang, Heng Zhang, Hui Jiang, Xuemei Zhao,*Linlin Shi,*Xinju, Zhu, Xinqi Hao, Maoping Song. Phathalocyanine Metal Complexes (M=Fe, Co, and Cu) Catalyzed Aerobic Oxidation of 2-Amino- benzyl Alcohols to Access Quinazolines and Quinolines.Chin.J. Org. Chem.2020, 40, 2755-2763. (Cover Article)

(8)Qiuling Wang,Linlin Shi, Shuang Liu, Changlei Zhi, Lian-Rong Fu, Xinju Zhu,* Xin-Qi Hao, and Mao-Ping Song.* Solvent-free and room temperature microwave-assisted direct C7 allylation of indolines via sequential C-H and C-C activation.RSC Adv.2020, 10,10883-10887.

(9)Jing Li,Linlin Shi, Shu-Ping Zhang, Xu-Yan Wang, Xinju Zhu,* Xin-Qi Hao, Mao-Ping Song.* Rh(III)-Catalyzed C−H Cyanation of 2HIndazole with NCyanoNphenylptoluene sulfonamide.J. Org. Chem.2020,85, 10835-10845.

(10)Jing Yan, Yan‐Bing Wang, Senyao Hou,Linlin Shi, Xinju Zhu, Xin‐Qi Hao, Mao‐Ping Song. NCC Pincer Ni (II) Complexes Catalyzed Hydrophosphination of Nitroalkenes with Diphenylphosphine.Appl Organomet Chem.2020, 5954.

(11)Ya-Gai Wang, Jing Li, Xiao-Die Wang,Linlin Shi. Xinju Zhu, Xin-Qi Hao, Mao-Ping Song. Rh(III)-catalyzed C–H acylmethylation of 2H-indazoles with sulfoxonium ylides.Journal of Saudi Chemical Society,2020,24, 850-856.

12.Zilin Liu, Xiaomin Wan, Huating Yan, Xuyan Wang,Linlin Shi,* Xinqi Hao and Maoping Song. NNN Pincer Ru(II)-Catalyzed Dehydrogenative Coupling of 2-Aminoarylmethanols with Nitriles for the Construction of Quinazolines.CCS· The 16th National Synthetic Organic Chemistry Symposium.

13.Changlei Zhi, Enling Huang, Xiaodie Wang, Binghui Liu,Linlin Shi,* Xinqi Hao and Maoping Song. Oxidative Sulfonamidomethylation of Imidazopyridines Utilizing Methanol as Main C1 Source.CCS·The 16th National Synthetic Organic Chemistry Symposium.

14.Jingna Wei, Zhaodong Jia, Ning Zhang,Linlin Shi,* Yan Xu, Xinqi Hao and Maoping Song. A new colorimetric and fluorescent chemosensor based on thiazolyl-hydrazone for sensitive detection of copper ions. CCS·The 16th National Synthetic Organic Chemistry Symposium.

15. Guoxing Liu, Juhua Leng, Qingyang Zhou, Zhe Deng, Linlin Shi,† Cailing Fan, Xiufang Xu, Mao-PingSong,Dyes and Pigments. https://doi.org/10.1016/j.dyepig.2022.110361.

16.  Linlin Shi,Dongdong An, Guang-Jian Mei*. Difluoromethylation of heterocycles via a radical process.Org. Chem. Front. 2022. 10.1039/d2qo00762b

17.Guoxing Liu, Juhua Leng, Qingyang Zhou, Zhe Deng,Linlin Shi*,Cailing Fan*. Fluorescence photoswitch of stiff-stilbene derivatives for anti-counterfeiting.Dyes and Pigments, 2022,203, 110361.

18.Yu-Shen Zhu†,Linlin Shi† (First Author),Lianrong Fu, Xiran Chen, Xinju Zhu, Xin-Qi Hao, Mao-Ping Song*. Iodine-catalyzed amination of benzothiazoles with KSeCN in water to access primary 2-aminobenzothiazoles.Chin. Chem. Lett.2022, 33, 1497-1500.

19. Yuting Xue,† Linlin Shi,†(First Author)Xu Wang, Xiaoni Yu, Xinju Zhu,* Xin-Qi Hao,* Mao-Ping Song. Regioselective N-F and α C(sp3)-H Arylation of Aliphatic NFluorosulfonamides with Imidazopyridines.Org. Lett. 2021,23, 6807.

20.Wenxiu Liu, Guoxing Liu, Xinju Zhu, Xin Han, Anting Lu, Shuai Lu, Linlin Shi,† Xin-Qi Hao, Mao-PingSong,2022,doi.org/10.1039/D2NJ00382A.

21.Ling-ling Miao, Xinju Zhu, Guoxing Liu, Xin Han, Wenping Xie, Shuai Lu, Long Zhang, Kai Wang, Linlin Shi,† Xin-Qi Hao and Mao-Ping Song,Chin. Chem. Lett.2022, Accepted

22. Jing-Jing Qu,Linlin Shi,† Yan-Bing Wang, Jing Yan, Tian Shao, Xin-Qi Hao, Jia-Xiang Wang, Hong-Yu Zhang, Jun-Fang Gong and Bing Song, Molecules2022, 27(10), 3106; https://doi.org/10.3390/molecules27103106.

23. Tiantian Li, Xinju Zhu, Hui Jiang,Linlin Shi,* Xin-Qi Hao, Mao-Ping Song.* Pd-catalyzed decarboxylative [3+2] cycloaddition: Assembly of highly functionalized spirooxindoles bearing two quaternary centers. Appl Organomet Chem., 2021, https://doi.org/10.1002/aoc.6516

24.Linlin Shi,* Tiantian Li,  Guang-Jiang Mei.* Recent advances in transition-metal-free C–H functionalization of imidazo[1,2-a]pyridines. Green Synth. Catal., 2022, https://doi.org/10.1016/j.gresc.2022.03.007 ( #contributed equally)

25. Tiantian Li,Linlin Shi,* Xin-Qi Hao, * Mao-Ping Song.* Visible-Light- Promoted Direct C(sp2)-H Radical Difluoromethylation of Duinoxalinones and Difluorosulfones. (manuscript in preparation)