臧双全,郑州大学化学学院博士生导师、学术副校长、郑州大学化学学院院长和绿色催化研究中心主任,河南省晶态分子功能材料重点实验室主任、河南省肿瘤诊疗团簇分子材料国际联合实验室中方负责人。主持包括国家杰出青年基金项目、国家基金委重大研发计划重点项目等多项重要科研项目。发表系列高水平研究论文,包括Nat. Chem.,Natl. Sci. Rev.,Sci. Adv.,Nat. Commun(2篇).,JACS (15篇).,Angew. Chem(18篇).,Adv. Mater(6篇).,Chem. Soc. Rev.,(3篇)等。所有发表论文被引用超过16000次,H-index为70。参与撰写3部英文专著。
邮箱:zangsqzg@zzu.edu.cn
学术头衔/兼职:国家杰出青年基金获得者、中原学者、英国皇家化学会会士、河南省自然科学一等奖获得者,河南省第十批省优秀专家。担任中国化学会分子聚集发光专业委员会副主任委员、河南省化学会副理事长、中国化学会晶体化学专业委员会委员、中国化学会分子筛专业委员会委员、中国化学会超分子化学专业委员会委员、中国感光学会光化学与光生物专委会委员、中国颗粒学会发光颗粒专业委员会委员、Wiley出版社《Aggregate》期刊副主编、《中国化学快报》副主编、ACS出版社《Crystal Growth & Design》期刊Topic Editor、《无机化学学报》编委。
研究方向:团簇化学
教育与工作简历:
2013.12-至今,郑州大学化学学院,教授
2008.08-2013.12,郑州大学化学学院,副教授
2006.08-2008.08,香港中文大学,博士后研究员
2003.09-2006.06,南京大学,无机化学,博士
2000.09-2003.06,河南大学,无机化学,硕士
1996.09-2000.07,河南大学,化学教育,学士
荣誉称号:国家杰出青年科学基金获得者、享受国务院特殊津贴专家、河南省高层次人才、河南省特聘教授、河南省学术技术带头人、河南省科技创新杰出青年、河南省教育厅学术技术带头人、河南省第十批省优秀专家、河南省高校科技创新人才、河南省高校青年骨干教师等。
获奖情况:荣获河南省自然科学奖一等奖一项、河南省优秀博士、硕士学位论文指导教师、宝钢优秀教师奖、郑州大学首届优良学风课堂任课老师等。
一、主持科研项目
国家自然科学基金项目及科技部项目
1.国家自然科学基金重大研究计划重点支持项目:金属团簇手性分级组装及功能调控研究(92061201),455万;
2.国家自然科学基金杰出青年基金项目:新型银硫团簇材料的定向合成与性能研究(21825106),400万;
3.国家重点研发计划项目(项目子课题):手性纳米结构的精准构筑及生物功能调控,100万;
4.国家自然科学基金面上项目:基于银硫簇的金属有机框架材料的构建及比率型荧光传感性能研究(21671175),80万;
5.国家自然科学基金面上项目:染料敏化的光捕获型金属有机框架材料的设计、制备及光催化产氢性能研究(21371153),80万;
6.国家自然科学基金青年项目:基于新型芳香多羧酸配体的孔洞配合物的合成及气体吸附性能研究(20901070),25万。
省部及其它基金资助项目
1.河南省科技创新团队项目:刺激响应型晶态分子智能材料(19IRTSTHN022),100万;
2.河南省科技创新杰出青年项目:新型清洁能源晶态分子催化材料的研发(164100510005),30万;
3.河南省科技厅创新人才项目:新型稀土-有机配位聚合物的构筑及发光性能研究(13HASTIT008),60万;
二、代表性论文
1.Ren-Wu Huang, Yong-Sheng Wei, Xi-Yan Dong, Xiao-Hui Wu, Chen-Xia Du, Shuang-Quan Zang*, Thomas C. W. Mak,“Hypersensitive dual-function luminescence switching of a silver-chalcogenolate cluster-based metal–organic framework”Nature Chemistry, 2017, 9, 689-697.
2.Yan Jin, Chong Zhang, Xi-Yan Dong, Shuang-Quan Zang*, and Thomas C. W. Mak,“Shell engineering to achieve modification and assembly of atomically-precise silver clusters”, Chem. Soc. Rev., 2021, 50, 2297-2319.
3.Hai-Yang Li, Shu-Na Zhao, Shuang-Quan Zang* and Jing Li,*“Functional metal–organic frameworks as effective sensors of gases and volatile compounds”Chem. Soc. Rev., 2020, 49, 6364-6401.
4.Xueli Zhao, Shuang-Quan Zang* and Xiaoyuan Chen*,“Stereospecific interactions between chiral inorganic nanomaterials and biological systems”Chem. Soc. Rev., 2020, 49, 2481-2503.
5.Zhen Han, Xi-Yan Dong, Peng Luo, Si Li, Zhao-Yang Wang, Shuang-Quan Zang*, Thomas C. W. Mak,“Ultrastable atomically precise chiral silver clusters with more than 95% quantum efficiency”Sci. Adv., 2020; 6, eaay0107.
6.Xi-Ming Luo, Chun-Hua Gong, Fangfang Pan, Yubing Si, Jia-Wang Yuan, Muhammad Asad, Xi-Yan Dong*, Shuang-Quan Zang*, and Thomas C. W. Mak,“Small symmetry-breaking triggering large chiroptical responses of Ag70 nanoclusters”, Nat. Commun., 2022, 13, 1177.
7.Xi-Yan Dong, Yu-Bing Si, Jin-Sen Yang, Chong Zhang, Zhen Han, Peng Luo, Zhao-Yang Wang, Shuang-Quan Zang*, and Thomas C. W. Mak,“Ligand engineering to achieve enhanced ratiometric oxygen sensing in a silver cluster-based metal-organic framework”, Nat. Commun., 2020, 11, 3678.
8.Yan Jin, Qiu-Chen Peng, Si Li, Hui-Fang Su, Peng Luo, Ming Yang, Xin Zhang, Kai Li,* Shuang-Quan Zang*, Ben Zhong Tang* and Thomas C. W. Mak,“Aggregation-induced barrier to oxygen (AIBO)—A new AIE mechanism for metal cluster with phosphorescence”, Natl Sci Rev, 2022, 9, nwab216.
9.Ying-Xue Yuan, Jing-Hui Jia, Yu-Pan Song, Feng-Ying Ye, Yan-Song Zheng,* and Shuang-Quan Zang*,“Fluorescent TPE Macrocycle Relayed Light-Harvesting System for Bright Customized-Color Circularly Polarized Luminescence”, J. Am. Chem. Soc., 2022, 144, 5389-5399.
10.Si Li, Xi-Yan Dong, Kong-Sheng Qi, Shuang-Quan Zang*, and Thomas C. W. Mak,“Full-Color Tunable Circularly Polarized Luminescence Induced by the Crystal Defect from the Co-assembly of Chiral Silver(I) Clusters and Dyes”, J. Am. Chem. Soc., 2021, 143, 20574-20578.
11.Jia-Hong Huang, Yubing Si, Xi-Yan Dong, Zhao-Yang Wang, Li-Ying Liu, Shuang-Quan Zang,* and Thomas C. W. Mak,“Symmetry Breaking of Atomically Precise Fullerene-like Metal Nanoclusters”, J. Am. Chem. Soc., 2021, 143, 12439-12444.
12.Miao-Miao Zhang, Xi-Yan Dong, Zhao-Yang Wang, Xi-Ming Luo, Jia-Hong Huang, Shuang-Quan Zang*, and Thomas C. W. Mak,“Alkynyl-Stabilized Superatomic Silver Clusters Showing Circularly Polarized Luminescence”, J. Am. Chem. Soc., 2021, 143, 6048-6053.
13.Zhi-Bing Sun, Ya-Nan Si, Shu-Na Zhao, Qian-You Wang,* and Shuang-Quan Zang*,“Ozone Decomposition by a Manganese-Organic Framework over the Entire Humidity Range”, J. Am. Chem. Soc., 2021, 143, 5150-5157.
14.Qian-You Wang, Jie Wang, Shan Wang, Zhao-Yang Wang, Man Cao, Chun-Lin He, Jun-Qing Yang, Shuang-Quan Zang* and Thomas C. W. Mak,“o-Carborane-Based and Atomically Precise Metal Clusters as Hypergolic Materials”, J. Am. Chem. Soc., 2020, 142, 12010-12014.
15.Jian Zhao, Tongjin Zhang, Xi-Yan Dong, Meng-En Sun, Chong Zhang, Xinlei Li, Yong-Sheng Zhao,* and Shuang-Quan Zang*,“Circularly Polarized Luminescence from Achiral Single Crystals of Hybrid Manganese Halides”. J. Am. Chem. Soc., 2019, 141, 15755-15760.
16.Man Cao, Rui Pang, Qian-You Wang,* Zhen Han, Zhao-Yang Wang, Xi-Yan Dong, Shun-Fang Li, Shuang-Quan Zang*, Thomas C. W. Mak.“Porphyrinic Silver Cluster Assembled Material for Simultaneous Capture and Photocatalysis of Mustard-Gas Simulant”. J. Am. Chem. Soc., 2019, 141, 14505-14509.
17.Zhao-Yang Wang, Meng-Qi Wang, Yan-Ling Li, Peng Luo, Tong-Tong Jia, Ren-Wu Huang, Shuang-Quan Zang*, Thomas C. W. Mak,“Atomically precise site-specific tailoring and directional assembly of superatomic silver nanoclusters”J. Am. Chem. Soc., 2018, 140, 1069-1076.
18.Si Li, Xiang-Sha Du, Bing Li, Jia-Yin Wang, Guo-Ping Li, Guang-Gang Gao, Shuang-Quan Zang*,“Atom-precise modification of silver(I) thiolate cluster by shell ligand substitution: a new approach to generation of cluster functionality and chirality”, J. Am. Chem. Soc., 2018, 140, 594-597.
19.Yong-Sheng Wei, Xiao-Peng Hu, Zhen Han, Xi-Yan Dong, Shuang-Quan Zang*, Thomas C. W. Mak,“Unique proton dynamics in an efficient MOF-based proton conductor”, J. Am. Chem. Soc., 2017, 139, 3505-3512.
20.Xi-Yan Dong, Bo Li, Bin-Bin Ma, Shi-Jun Li, Ming-Ming,Dong, Yan-Yan Zhu, Shuang-Quan Zang*, You Song*, Hong-Wei Hou, Thomas C. W. Mak*,“Ferroelectric switchable behavior through fast reversible de/adsorption of water spirals in a chiral 3D metal-organic framework”, J. Am. Chem. Soc., 2013, 135, 10214-10217.
21.Li-Juan Liu, Zhi-Yuan Wang, Zhao-Yang Wang, Rui Wang*, Shuang-Quan Zang*, Thomas C. W. Mak,“Mediating CO2 Electroreduction Activity and Selectivity over Atomically Precise Copper Cluster”, Angew. Chem. Int. Ed. 2022, 61, e202205626.
22.Jie Wang, Fan Xu, Zhao-Yang Wang*, Shuang-Quan Zang*, Thomas C. W. Mak,“Ligand-Shell Engineering of a Au28 Nanocluster Boosts Electrocatalytic CO2 Reduction”, Angew. Chem. Int. Ed. 2022, 61, e202207492.
23.Qian-You Wang, Jing Liu, Man Cao, Jia-Hua Hu, Rui Pang, Shan Wang, Muhammad Asad, Yong-Li Wei, Shuang-Quan Zang*,“Aminal-linked Porphyrinic Covalent Organic Framework for Rapid Photocatalytic Decontamination of Mustard-Gas Simulant”, Angew. Chem. Int. Ed. 2022, 61 e202207130.
24.Yi-Man Wang, Jinmeng Cai, Qian-You Wang, Yao Li, Zhen Han, Si Li, Chun-Hua Gong, Shan Wang*, Shuang-Quan Zang*, Thomas C. W. Mak,“Electropolymerization of Metal Clusters Establishing a Versatile Platform for Enhanced Catalysis Performance”, Angew. Chem. Int. Ed. 2022, 61, e202114538.
25.Yuan-Yuan Liu, Xin Zhang, Kai Li,* Qiu-Chen Peng, Yu-Jing Qin, Hong-Wei Hou,* Shuang-Quan Zang*, and Ben-Zhong Tang*,“A New Kind of RIV-type AIEgens and Their Applications for the Construction of Multifunctional Luminescent MOFs”, Angew. Chem. Int. Ed. 2021, 60, 22417-22423.
26.Ying Zang, Chunxia Mi, Rui Wang, Hong Chen, Peng Peng,* Zhonghua Xiang,* Shuang-Quan Zang,* and Thomas C. W. Mak,“Pyrolysis-Free Synthesized Catalyst towards Acidic Oxygen Reduction by Deprotonation”, Angew. Chem. Int. Ed. 2021, 60, 20865-20871.
27.Wei-Miao He, Zhe Zhou, Zhen Han, Si Li, Zhan Zhou,* Lu-Fang Ma, and Shuang-Quan Zang,*“Ultrafast Size Expansion and Turn-On Luminescence of Atomically Precise Silver Clusters by Hydrogen Sulfide”, Angew. Chem. Int. Ed. 2021, 60, 8505-8509.
28.Jie Wang, Zhao-Yang Wang,* Shi-Jun Li, Shuang-Quan Zang,* and Thomas C. W. Mak,“Carboranealkynyl-Protected Gold Nanoclusters: Size Conversion and UV-Vis-NIR Optical Properties”, Angew. Chem. Int. Ed. 2021, 60, 5959-5964.
29.Jin-Sen Yang, Zhen Han, Xi-Yan Dong, Peng Luo, Hui-Lin Mo,* and Shuang-Quan Zang*,“Extra Silver Atom Triggers Room-Temperature Photoluminescence in Atomically Precise Radarlike Silver Clusters”, Angew. Chem. Int. Ed. 2020, 59, 11898-11902.
30.Miao-Miao Zhang, Xi-Yan Dong, Zhao-Yang Wang, Hai-Yang Li, Shi-Jun Li, Xueli Zhao, Shuang-Quan Zang*,“AIE Triggers the Circularly Polarized Luminescence of Atomically Precise Enantiomeric Copper(I) Alkynyl Clusters”, Angew. Chem. Int. Ed. 2020, 59, 10052-10058.
31.Yu-Jin Kong, Zhi-Ping Yan, Si Li, Hui-Fang Su, Kai Li, You-Xuan Zheng, and Shuang-Quan Zang*,“Photoresponsive Propeller-like Chiral AIE Copper(I) Clusters”Angew. Chem. Int. Ed., 2020, 59, 5336-5340.
32.Yan Jin, Si Li, Zhen Han, Bing-Jie Yan, Hai-Yang Li, Xi-Yan Dong, Shuang-Quan Zang*,“Cations Controlling the Chiral Assembly of Luminescent Atomically Precise Copper(I) Clusters”, Angew. Chem. Int. Ed. 2019, 58, 12143 -12148.
33.Si Li, Zhao-Yang Wang, Guang-Gao Gao, Bing Li, Peng Luo, Yu-Jin Kong, Hong Liu, Shuang-Quan Zang*,“Smart transformation of POSS shell controlled by thiolate silver(І) nanoclusters core in cluster@clusters dendrimers”. Angew. Chem. Int. Ed. 2018, 57, 12775-12779.
34.Ren-Wu Huang, Xi-Yan Dong, Bing-Jie Yan, Xiang-Sha Du, Dong-Hui Wei, Shuang-Quan Zang*, Thomas C. W. Mak,“Tandem silver cluster isomerism and mixed linkers to modulate the photoluminescence of cluster-assembled materials”, Angew. Chem. Int. Ed., 2018, 57, 8560-8566.
35.Hong Liu, Chao-Yu Song, Ren-Wu Huang, Yu Zhang, Hong Xu, Mei-Jia Li, Shuang-Quan Zang*, Guang-Gang Gao*,“Acid-base-triggered structural transformation of a polyoxometalate core inside a dodecahedrane-like silver thiolate shell”, Angew. Chem. Int. Ed., 2016, 55, 3699-3703.
36.Xi-Yan Dong, Mei Zhang, Ru-Bo Pei, Qian Wang, Dong-Hui Wei, Shuang-Quan Zang*, Yao-Ting Fan, Thomas C. W. Mak,“A crystalline copper(II) coordination polymer for the efficient visible-light-driven generation of hydrogen”, Angew. Chem. Int. Ed., 2016, 55, 2073-2077.
37.Yue Hua, Jia-Hong Huang, Zi-Hui Shao, Xi-Ming Luo, Zhao-Yang Wang, Jun-Qi Liu, Xueli Zhao*, Xiaoyuan Chen*, Shuang-Quan Zang,“Composition-Dependent Enzyme Mimicking Activity and Radiosensitizing Effect of Bimetallic Clusters to Modulate Tumor Hypoxia for Enhanced Cancer Therapy”, Adv. Mater. 2022, 34, 2203734.
38.Chong Zhang, Zhong-Shan Li, Xi-Yan Dong*, Yun-Yin Niu, Shuang-Quan Zang*,“Multiple Responsive CPL Switches in an Enantiomeric Pair of Perovskite Confined in Lanthanide MOFs”, Adv. Mater. 2022, 2109496.
39.Shu-Na Zhao, Jun-Kang Li, Rui Wang, Jinmeng Cai, Shuang-Quan Zang,*“Electronically and Geometrically Modified Single-Atom Fe Sites by Adjacent Fe NPs for Enhanced Oxygen Reduction”, Adv. Mater. 2022, 2107291.
40.Zhi-Peng Wu, Huabin Zhang, Shouwei Zuo, Yan Wang, Song Lin Zhang, Jing Zhang, Shuang-Quan Zang*, and Xiong Wen (David) Lou*,“Manipulating the Local Coordination and Electronic Structures for Efficient Electrocatalytic Oxygen Evolution”, Adv. Mater. 2021, 2103004.
41.Xiao-Yu Dong, Ya-Nan Si, Qian-You Wang, Shan Wang,* and Shuang-Quan Zang*,“Integrating Single Atoms with Different Microenvironments into One Porous Organic Polymer for Efficient Photocatalytic CO2 Reduction”, Adv. Mater. 2021, 2101568.
42.Chong Zhang, Zhi-Ping Yan, Xi-Yan Dong, Zhen Han, Si Li, Ting Fu, Yan-Yan Zhu, You-Xuan Zheng,* Yun-Yin Niu,* and Shuang-Quan Zang*,“Enantiomeric MOF Crystals Using Helical Channels as Palettes with Bright White Circularly Polarized Luminescence”, Adv. Mater., 2020, 38, 2002914.
43.Rui Wang, Xi-Yan Dong, Jiao Du, Jin-Yan Zhao, Shuang-Quan Zang*,“MOF-derived bifunctional Cu3P nanoparticles coated by an N,P-codoped carbon shell for hydrogen evolution and oxygen reduction”, Adv. Mater., 2018, 30, 1703711.