厚德笃学 惟实励新

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张灵志

姓名张灵志

所属学院化学与生物工程学院

导师类别硕士生导师

个人简述 

张灵志:男,1969年生,博士,研究员,博士生导师,中国科学院“百人计划”人才,广西区“特聘专家”,国家科学技术奖评审专家。1997毕业于中山大学高分子研究所,获得博士学位,是中科院广州能源所有机能源材料创新团队负责人。曾在中山大学、台湾大学、法国国家科学研究中心、纽约城市大学、Wisconsin大学等地从事教学和科研工作,目前主要从事锂离子电池、超级电容和有机太阳能电池等能量储存及转化器件的基础及应用开发研究。开发的有机硅电解质材料已由美国风险投公司资助的Silatronix Inc.公司作为Senior Research Scientist和公司部分股权持有人进行商业化开发。

主要进修访学经历及学术兼职

2009-至今中国科学院广州能源研究所,研究员,科学院"百人计划",从事新能源材料及其在电化学储能器件和有机太阳能电池方面的研究开发。

2005-2009美国Silatronix Inc.公司(Senior Research Scientist)和美国University of Wisconsin-Madison(Research Associate/Assistant Scientist)从事有机硅能量存储电解质材料开发及电化学性能和器件(超级电容及锂电池)的研究。

2004-2005美国纽约城市大学(Research Associate),从事有机共轭聚合物纳米材料制备及其在电开关应用方面的研究。

2003-2004法国国家科学研究中心Rennes化学研究所(CNRS Research Associate),从事含磷五员杂环phosphole共轭化合物及其金属配合物材料的有机金属化学合成工作。

2000-2002台湾大学化学系(合作研究),从事有机杂环共轭小分子和共轭聚合物的设计合成及其电致发光器件制作和发光性能。

1997-2000中山大学高分子研究所(讲师/副研究员),非线性光学材料合成及性能,聚合物的光学全息记录以及激光微结构成型加工。

学术兼职

美国化学学会会员(2004-至今)

国家科学技术奖评审专家

学科领域 

应用化学及能源新材料

研究方向

有机光电材料和纳米材料,尤其是新型电解质材料(包括室温离子液体、燃料电池固体聚合物膜材料等)和功能化碳纳米管等电极材料,及其在各种能量存储转化器件(如超级电容、燃料电池)方面的应用。

主要科研项目

主持的国家自然基金项目:

(1)负责人,“有机硅绿色电解质材料在电化学储能器件中的应用基础研究”,国家自然科学基金,2009 。

(2)主要负责人,“高安全性锂离子动力电池关键材料的产业化”,2009年广东省中国科学院全面战略合作计划项目,负责人,2009。

(3)负责人,“有机硅电解质材料的应用开发”,中国科学院海外杰出人才“百人计划”,2010。

(4)参与(佛山精进能源有限公司主持),“高安全性有机硅电解液及其在动力电池上的应用研究“,中科院院地合作项目,2011。

(5)负责人, “Cascading of Second Order Nonlinear Optical Polymer And All-Optical Switch Applications”, The Natural Science Foundation of Guangdong Province (Grant No. 980346); 1998。.

(6)负责人, “Formation And Manipulation of Micropatterns Fabricated in Polymer Films by Laser Holography”, the Natural Science Foundation of Guangdong Province (Grant No. 001249), 2000。.

主要成果 

1.在国际上首次报道了自由基和阳离子同时光引发交联而获得非线性光学(NLO)聚合物互穿网络(IPN)体系,所制备材料具有高NLO系数和优良的热稳定性。详细研究了含偶氮苯功能聚合物光信息存储性能和光致各向异性的机理,提出了一个新的动力学模型,并用计算机对动力学过程进行了数字模拟。此领域在国内外刊物发表论文30余篇。

2.在有机共轭杂环及共轭聚合物发光材料的合成开发和有机发光二极管器件方面进行了深入的研究,在学术及应用方面取得相当成果。

1)设计合成了全新的非芳香叔胺类呋喃共轭杂环的空穴传输材料,并申请了美国专利,已转让给全球最大光罩护膜供应商美国加州Micro Lithography Inc.。

2)首次以一锅法(one-pot)合成具有独特的电化学性能的含磷五员杂环金属有机化合物,此工作在国际刊物Organometallics,Chem. Commun.发表。

3.首次制备了具有优良的电开关性能的聚噻吩类(PEDOT)纳米针,已申请美国和世界专利,并已发表在国际刊物Advanced Materials。

4.设计开发了新型有机硅基电解质材料,包括室温离子液体,离子塑性晶体材料(Ionic PlasticCrystals)等,并研究了这些材料的电化学性能及其电能存储器件(锂电池和超级电容)的应用。创新点在于这些材料具有优良的安全性且环境友好,良好的电化学性能,以及极其简单的合成生产工艺(一步净反应,neat reaction)。已申请美国专利4项,并已转让于美国工业界Silatronix Inc.公司。


代表性论文:

1.Yue Lu, Wang Suqing, Zhao Xinyue, Zhang Lingzhi*,Nano-Silicon Composites Using Poly(3,4-ethylenedioxythiophene):Poly (styrenesulfonate) as Elastic Polymer Matrix And Carbon Source for Lithium-Ion BatteryAnode,Journal of MaterialsChemistry,DOI: 2012,10.1039/C1JM14568A.

2.秦雪英,汪靖伦,张灵志*,锂离子电池有机硅电解液的研究进展,化学进展,2011,已接收。

3.Zhang, L.Z.;Harring S.; Straughan M.; Zhang Z.C.; Butorac R.; Lyons L.; Amine K.; West R. (2010):Synthesis and Characterization of Alkylsilanes with Oligoethylene Oxide Substitutents for Safe Electrolytes in Lithium-Ion Batteries,Journal of MaterialsChemistry,20, 8224-8226(2010).

4.Zhang, L.Z., Zhang Z.C.; Harring, S.; Straughan, M.; Butorac, R.; Lyons, L.; Amine, K.; West, R.:Highly Conductive Trimethylsilyl Oligo(Ethylene Oxide) Electrolytes For Energy Storage Applications,Journalof Materials Chemistry,18(31), 3713-17 (2008).

5.Talance, V.L.; Hissler M.;Zhang L.Z.; Karpati, T.; Nyulaszi, L.; Caras-Quintero, D.; Ba¨uerle, P.; Regis, R.: Synthesis, electronic properties And electropolymerisation of EDOT-capped Phosphole,Chem. Commun., 2200-2002(2008).

6.Chen, Z.; Wang, H.;Vissers, D. R.;Zhang, L. Z.; West, R.; Lyons, L. J.; Amine, K. (2008):Kinetic Investigation of the Solvation of Lithium Salts in Siloxanes”,J. Phys. Chem. C.;112(6); 2210-2214(2008).

7.Chen, Z.H.;Zhang, L.Z.;West, R.; Amine, K.:Gel Electrolytes for Lithium-Ion Batteries,Electrochem. Acta,53, 3262-3266(2008).

8.Tse, K.Y.;Zhang, L.Z.;Baker, S.E.; West, R.; Hamers, R.J. Interfacial Capacitane of Verticall-aligned carbon nanofibers in organosilicon electrolytes:Electrical Properties of a High-StabilityNanostructured Electrochemical Interface,Chemistry of Materials,19(23); 5734-5741(2007).

9.Zhang, L.Z.; Bikzhanova Galina A.; West R.: Trimethyl-(2-hydroxyethoxyethyl) Ammonium Iodide,Acta Crystallographica Section E,E63(5), o2284-o2285(2007).

10.Su K.; Nuraje N.;Zhang, L.Z.;Chu I.-W.; Petz R.M.; Matsui H.; Yang N.L.: Single crystalline nanoneedles with fast conductance switching properties from interfacial crystallization polymerization of3, 4-ethylenedioxythiophene,Advanced Materials,19(5),669-672(2007).

11.Viachesla Dvementiev,Zhang, L.Z.; West, R. ; Hamers, R. ;Tse, K..-Y.:The 15thInternational Seminar on Double Layer Capacitors And Hybrid Energy Storage Devices, Florida, pp. 36-45(2005).

12.Zhang, L.Z.;Hissler, M.;Bäuerle, P.; Lescop, C.; Réau, R. (2005): A Study of Mono- And 1,1¢-Di-Phosphaferrocenes As Building Blocks forp-Conjugated Systems,Organometallics, 24, 5369(2005).

13.Niu Y.P.;Zhang, L.Z.;Su, Y.Z.; Liang, Z.X.; Lu, W.; She, W.L. (2005): High-density optical storage And three-dimension nested microstructures of an azobenzene polymer film.Gongneng Gaofenzi Xuebao18(1),6.

14.Niu, Y.P.;Zhang, L.Z., Su, Y.Z.; Liang, Z.X.; Lu, W.; She, W.L. (2004): Molecular reorientation mechanism of gratings structure in an azobenzene polymer (PGMAA-20) film,Ganguang Kexue Yu Guang Huaxue,22(3), 183-189.

15.Xu, Y.K.; Cai, Z.G.; Qi, X.L.; Wang, F.J.;Zhang, L.Z.;Niu, Y.P.; Liang, Z.X. (2004): Study of square microstructure on polymer films made with a novel step-by-step procedure.Guangxue Xuebao,24(11),1455-1458.

17.Niu, Y.P.;Zhang, L.Z.;Li, H.S.; Liang, Z.X. (2004): Synthesis And photoreduction behavior of novel polymer liquid crystals containing viologen units.Zhongshan Daxue Xuebao, Ziran Kexueban,43(1),51-55.

18.Wang, J.;Zhang, L.Z.;Liang, Z.X.; Xu, Z.D.; Cai, Z.G.,;She, W.L.; Zhou, J.Y. (2003): Photo-induced Birefringence Phenomenon of A Double Azo PolymerPolym.Intern.,52,1165-1168.

19.Zhang, L.Z.*;Wang, J.; Liang, Z.X.; Xu, Z.D.; Cai, Z.G; She, W.L.; Zhou, J.Y. (2003): Photoinduced Micropattern in Azobenzene Polymer Film,Chinese Science Bulletin

(Eng.), 48(3), 244-246

20.Zhang, L.Z.; Chen, C.-W.; Lee, C.-F; Wu, C.-C; Lee, G.-H.; Yu, W.; Luh, T.-Y. (2002): Non-Amine-Based Furan-Containing Oligoaryls as Efficient Hole Transporting Materials,Chemical Communications,2336-2337.

21.Li, Yu; Niu, Yong-ping; Liang, Ru;Zhang, Ling-zhi; Cai, Zhi-gang; Liang, Zhao-xi. Synthesis And NLO properties of novel photocrosslinked IPN system.Gongneng Gaofenzixuebao,2003, 16(2), 132-136.Wu, C.-F;Hung, W-Y; Liu,T.-L.;Zhang, L.Z.; Luh, T.-Y. (2002):Hole-transport properties of a furan-containing oligoaryl.Journal of AppliedPhysics, 93(9), 5465-5471.

22.Zhang, L.Z.*; Cai, Z.G.; Ninulescu, V.; Xie, Z.H.; Jin, K; Liang, Z.X. (2001): Photoinduced Birefringence And Numerical Solution of a New Dynamic Model in an Amorphouse Copolymer Containing Azobenzene Groups.Chin. J. Polym. Sci.,19, 255-263.

23.Wang, J.;Zhang, L.Z.;Chen, Y.L.; Liang, Z.X.; Cai, Z.G. (2002); Synthesis And second-order nonlinearity of new organic/inorganic network by sol-gel process.Ganguang Kexue Yu Guang Huaxue,20(4),276-282.

24.Lu, W.; She, W.L.;Zhang, L.Z.*,(2002): Characterization of photoinduced birefringence in the azobenzene doped polymer films,Zhongguo Jiguang,A29(9),845-849.

25.Xu, Y.K.; Cai, Z.G.;Zhang, L.Z.; Qi, X.L.; Liang, Z.X. Optimized math"s model of photoinduced birefringence in amorphous copolymer containing azobenzene groups,Zhongguo Jiguang,A29(9),841-844.

26.Song, Hua-Can; Sun, Yi-Feng; Li, Wei-Ming; Xu, Zun-Le;Zhang, Ling-Zhi; Cai, Zhi-Cang (2001): Second nonlinear polarizability of 4-substituted-benzylideneoxazol-5(4H)-ones And 9-substituted-phenylacridines.Huaxue Xuebao,59(10),1563-1565. .

27.Huang, Xiao; Wang, Jian;Zhang, Ling-Zhi; Cai, Zhi-Gang; Liang, Zhao-Xi. (2001): Preparation And second-order optical nonlinearity of novel phenoxysilicon networks by sol-gel process.Chin. J. Polym. Sci.,19(1),39-44.

28.Li, Z., Xu; Z.D., Liang, L.Z.; Cai, Z.G., Zhou, J.Y.;Zhang, L.Z.;Liang, Z.X. (2001): Photoinduced hexagonal symmetry microstructure in azobenzene polymer films.Guangxue Xuebao,21(4),491-494.

29.Liang, X.X.;Zhang, L.Z.;Wang, J.; Cai, Z.G.; Liang, Z.X. (2001): Synthesis And thermotropic liquid crystalline behavior of two polyethers containing stilbene groups.Gaofenzi Xuebao,(1),109-113.

30.Wang, X.; Su, H.;Zhang, L.Z.; He, Y. J.; Zheng, X.G.; Wang, H. Z. (2001): A novel method for fabrication of sub-micrometer crystalline structure by holography.Applied Optics,l40, 5588-5591.

31.Chen, H.-J.;Zhang, L.-Z.;Cai, Z.-G.;Yang, G.;Chen, X.-M. (2000):Organic-inorganic hybrid materials assembled through weak intermolecular interactions. Synthesis, structures And non-linear optical properties of [4,4"-bipyH2][M(NCS)4] (M = Mn2+1, Co2+2 or Zn2+3 ; 4,4"-bipy = 4,4"-bipyridine).DaltonTransactions,(14), 2463-2466

32.Yang, G.; Zhu, H.G.;Zhang, L.Z.;Chen, X. M.(2000): Synthesis, structure And second harmonic effect of bis(m-2-3,5-dinitrobenzoato)zinc(II) And tetraaquabis(3,5-dinitrobbenzoato-)cobalt(II) tetrahydrate.Australian Journal of Chemistry,53, 601-605.

33.Xu, Z.D.; Cai, Z.G.; Zhang, L.Z.; Liu, Y.F.; Yang, J.; She, W.L.; Zhou, J.Y. (2000): Pattern Formation And Quasicrystal Structure in Azobenzene Polymer Film.Chin. Phys. Lett.(Eng.),12,428-430.

34.Zhang, L.Z.*; Li, Y.; Liang, Z.X.; Yu, Q.S.; Cai, Z.G. (1999): New Crosslinked Polymer Systems with High And Stable Optical Nonlinearity.Reactive & Functional Polymers,40, 255-262.

35.Zhang, L.Z.*; Cai, Z.G.; Xu, Z.D.; Yu, Q.S.; Liang, Z.X. (1999): Second Order Nonlinear Optical Interpenetrating Polymer Networks Based on Polyurethane or Poly(Methyl Methacrylate) And Epoxy Polymer.Polymer International,48, 467-472.

36.Zhang, L.Z.*; Cai, Z.G.; Yu, Q. S.; Liang, Z. X. (1999), Photocrosslinked Polymer And Interpenetrating Polymer Network for Nonlinear Optics.Journal of Applied Polymer Science,71, 1081-1087.

37.Zhang, L.Z.*; Cai, Z.G.; Ying, Q.D.; Liang, Z.X. (1999): An Epoxy/(Methyl methacrylate) Interpenetrating Polymer Network for Second-Order Nonlinear Optics.Chinese Journal of Polymer Science(Eng.),17, 435-440.

38.Bi, D.Y.;Zhang, L.Z.; Liang, Z.X.; Liu, S.H. (1997): Optical Information Storage in Poly [3¢- methyl-4¢-bis(N,N-hydroxyethyl) amino-4-nitro-azobenzene sebacoyl] Film by Degenerate Four-Wave Mixing,Chinese Physics Letters(Eng.),14, 284-286.

39.Zhang, L.Z.*; Guo, J.M.; Liang, Z.X.; Bi, D.Y.; Liu, S.H.; Cai, Z.G.; Lin, W.Z. (1997): Synthesis And third-order nonlinear optical characteristic of an azobenzene polymer (PAZOS).Gongneng Gaofenzi Xuebao,10(4),463-469.

40.Zhang, L.Z.*; Feng M.H.; He Y.; Liang, Z.X. (1995): Novel Liquid Crystal Ionic Polymers Containing Viologen Units,Transactions of the Nonferrous Metals Society of China,5(2),539.